Literature summary extracted from

Sole, J.; Brummund, J.; Caminal, G.; Schuerman, M.; Alvaro, G.; Guillen, M.
Trimethyl-epsilon-caprolactone synthesis with a novel immobilized glucose dehydrogenase and an immobilized thermostable cyclohexanone monooxygenase (2019), Appl. Catal. B, 585, 117187 .

No PubMed abstract available

Application

EC Number	Application	Comment	Organism
1.14.13.22	synthesis	synthesis of trimethyl-epsilon-caprolactone using cyclohexanone monooxygenase immobilized on Mana-agarose and a highly active glucose dehydrogenase for cofactor regeneration. A biocatalyst yield of 37.3 g trimethyl-epsilon-caprolactone per g of CHMO and 474.2 g trimethyl-epsilon-caprolactone per g of glucose dehydrogenase are obtained	Thermocrispum municipale

Cloned(Commentary)

EC Number	Cloned (Comment)	Organism
1.14.13.22	expression in Escherichia coli	Thermocrispum municipale

Organism

EC Number	Organism	UniProt	Comment	Textmining
1.14.13.22	Thermocrispum municipale	A0A1L1QK39	-	-
1.14.13.22	Thermocrispum municipale DSM 44069	A0A1L1QK39	-	-

Substrates and Products (Substrate)

EC Number	Substrates	Comment Substrates	Organism	Products	Comment (Products)	Rev.	Reac.
1.14.13.22	3,3,5-trimethyl-cyclohexanone + NADPH + H+ + O2	-	Thermocrispum municipale	trimethyl-epsilon-caprolactone + NADP+ + H2O	-	?
1.14.13.22	3,3,5-trimethyl-cyclohexanone + NADPH + H+ + O2	-	Thermocrispum municipale DSM 44069	trimethyl-epsilon-caprolactone + NADP+ + H2O	-	?

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Release 2023.1 (January 2023)